It depends whether it takes two earners to reach $250,000 per year. Consider two single-parent families, each with two children, each earning $125,000 per year. To me, that's middle-class -- barely, when you consider the amount of paid help (e.g. day-care) required.
Now, suppose these two married -- resulting in a single family with two earners and four children. It boggles the mind to think that a simple marriage licence could make six middle-class people rich.
So maybe you should measure wealth by dividing the income by a weighted average of the number of family members, giving a heavier weight to adults in the family.
If you want to argue that two can live as cheaply as one, and that a married family is indeed richer than two smaller families at the same income-per-person, then the most important thing the government could possibly do as an anti-poverty measure would be to strongly discourage single motherhood. (What can you say about a government that would financially penalize sexual morality in order to better subsidize fornicators?)